Boone is a destroyer. Give him the All-American with a bunch of 5.56
Yup. The AA has a relatively short range so it's good for companions if you want to be a bit closer to you (not so far behind) or in places like Vaults, vs. an actual sniper rifle. Ammo is cheap & plentiful bu they'll go through it like water in a sieve.
It sort of depends on what you mean by 'straightforward' - non-VATS melee? Charging in, guns blazing, spamming the fire key? (?)
Boone, Cassidy, and Raul are Guns tagged and will do well with those weapons.
Arcade is Energy weapons (he won't use many outside of his powerful default plasma gun tho)
Veronica is Melee or Energy weapons if you want her to be ranged.
Lily is Melee with a high Sneak (the rest are terrible at sneaking/will be seen)