» Fri May 11, 2012 1:12 am
Your Enchanting skill determines the percentages and figures involved with your new enchantments, so for example when my Enchanting skill was low I could only get about 10% Frost Resistance on an armour piece, even using a Grand Soul Gem. Now my Enchanting skill is higher, I can get 15% and higher.
The Smithing skill seems to affect how much you can upgrade your armour - for example I picked the Steel Smithing perk early on, and when my skill was about 30ish I could improve Steel armour to "Superior." Now my Smithing skill is 69 or so, though, I can improve Steel armour to "Flawless."
I'd imagine Alchemy is also affected in the same way. You can probably get higher damage/heals and longer duration on your poisons and potions. I've not really done Alchemy yet though so I can't say for sure.
Skills and perks both affect damage etc. in general, though.