The character you describe is what I plan on doing my next play through. I envision him as a Ranger, living off the land like you said.
Here are some of the skills I think would make a great Ranger. I didn't include all the skills you might need, just some of the good ones.
Archery - Overdraw, Eagle Eye, Critical Shot, Steady Hand, Power Shot, Ranger, Quick Shot, Bullseye
Sneak - Stealth, Muffled Movement, Deadly Aim, Silence
Alchemy - Alchemist, Poisoner, Concentrated Poison
One-hand - Armsman, Dual Flurry (maybe)
Light Armor - Agile Defender, Custom Fit, Unhindered
I would use poisons as much as possible, light armor (obviously) and daggers as your back-up weapon. Daggers are the closest thing to a hunting knife that I can think of. Maybe an axe just in case you have to chop some tress down to make a shelter when out living off the land.