Smithing is the easiest skill to level up among all skills.
The merchant in Riverwood, and the 3 merchants you have, including skyforge, in whiterun, fills up their stock of minerals every day.
And since you only need to make iron daggers to level up.
Basically every run into a dungeon you do, will give you enough cash to create 50-75 iron daggers.
Considering it takes 10 iron daggers to level 1 skill point between 90 to 100, you can imagine how few it takes to get the lower levels.
Add in the weapons and armors you do for yourself as well, your smithing is probably around 40-60% higher then all your other skills.
Smithing is by far, the easiest.
I would have to say pickpocketing definately sounds like it.
I find Alchemy to level extremly slowly as well.