To perform the bite, the enemy needs to be at low health, enough to be killed by a power claw attack, hold down the attack trigger while standing still and facing your opponent. Most of the time this will execute the power attack bite, however other factors such as enemy position and elevation can cause you to perform a regular claw power attack. hope this helps

(please note, It doesn't seem to work if you are moving, so standing still is important)
(also if possible, get them to such low health that they are on the floor begging for mercy, I find it much easier this way)