Spouses yes, follower's I've only been able to turn one and that was my housecarl in solitude. You won't be able to turn quest giver NPC's like Aela the huntress and such.
Hmm, I wonder about those you have finished all quests for. I role play a lot. Okay, really long role play short. Karjio and I are good friends. did a lot of vampire hunting. (Like stopping the Morthal thing) I role played, and it's at the point where I've revealed to him that I was infected at Morthal, he was fine, I told him the benefits, he would be fine with joining me. So I'd like to be able to make him a vampire for role playing reasons.