With the landscape editor open:
1-9 set the brush size to 1-9 instantly.
S toggles 'smoothing' mode.
F toggles 'flatten' mode.
Control+Right click sets the active texture to the one you right click on.
H Opens and closes the landscape editor.
Those are the main ones I use. (Well except flatten, I never ever use that as the results look horribly unnatural)