When do they become worse than what I can make? Or do they?
I have some knowledge of bound weapons and what they're like. According to the UESP, with the Mystic Binding perk, the Bound Battleaxe (my choice) has a base damage of 22. That's about the same as an unsmithed Elven Battleaxe or Warhammer.
The character I plan to use them on is currently at 30 Smithing with a Dwarven Greatsword smithed to Superior. IIRC, it does little less than 40 damage at 50-something Two-Handed. Would a Bound Battleaxe be better or should I save a couple of perks and just keeping using what I can find/make and improve?