In Skyrim, mostly I've only used the http://www.uesp.net/wiki/Skyrim:Muffle_(effect) effect to enhance stealth; I've not built up a character's illusion skill enough to use http://www.uesp.net/wiki/Skyrim:Invisibility, which would obviously be useful.
http://www.uesp.net/wiki/Skyrim:Fear and http://www.uesp.net/wiki/Skyrim:Pacify seem like they would be useful, though in any situation I might use them, I've tended to use a destruction spell or other attack instead. This is complicated by the limited range of levels on which a given variation of the spell is useful. In past games, I've seen spells with descriptions similar to http://www.uesp.net/wiki/Skyrim:Frenzy to be used in exploits to force a non-hostile character to attack, but I've never had a situation in Skyrim where I've wanted to do that. I have a really hard time believing that http://www.uesp.net/wiki/Skyrim:Rally would be useful.
Does anyone have tips for use of these spells?