of the people that work on moding the game and have created new weapons and or armor.

could any one direct me to a tutorial on making metal for shields, armor and blades in photo shop, google doesnt help me very much in this search.

You could go to the Skyrim Mods sub-forum, they would probably have better information. The Creation Kit sub-forum could also help.

In the Creation Kit forums there are a number of http://www.gamesas.com/topic/1343653-creation-kit-video-tutorials-merged/, including one on armor

This site will help you with everything you need:

http://www.creationkit.com/