AMD may need a bit of a push to get the Crossfire profile out. Someone from the AMD support board said if we want a crossfire profile made for New Vegas then to use the catalyst feedback form and request it. He wrote the more people that request it, the higher it'll be put on the priority list. It's hard to believe someone on the Catalyst team isn't already playing the game and realizing it's missing. Kids these days. And no, the d3d9.dll trick does not give you full CrossfireX Power ™.

Anyways, here is the http://www.amdsurveys.com/se.ashx?s=5A1E27D27E29B0E3 to submit a request for Fallout New Vegas crossfire.

For anyone who doesn't know what crossfire is, it's when you have multiple AMD Radeon GPUs working together. If you're an nVidia user then it's called SLI.

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