Pickpocketing when using the thief stone levels up amazingly fast. You essentially need one perk to get it to a point that you have 60-70% chance to loot any unenchanted jewelry, and two perks into the first pickpocket perk gets you around 90%. Walk to any random NPC, stand right in front of them, doesn't matter if you're detected or not, and you can gain 2-3 levels in pickpocketing from one NPC if they have any jewelry or gems on them(and almost everyone does). This just might be the fastest skill to level in the game aside from smithing, and makes money a lot faster than smithing(if you have a fence available) since you don't need to go and enchant your daggers and get soul stones in between working the skill.
Not to mention you can use this for a lot of fun. I was hit by the quest where the thief runs up to you and hands you something, then the owner comes asking about him, gave the item to the rigthful owner, killed the thief, then turned around and pickpocketed the item off the hunter. I also walked right up to maven black briar, tok her personal key and key to her manor, as well as all her jewelry while she stood there and talked down to me.
The final advantage is that you can gain a TON of useful enchants this way. I've found almost every skill enchant and resist enchant just sitting on jewelry in NPC inventories and just lifted it right off of them.