There're plenty of items you cannot access. They're part of the 'hidden inventory' of a NPCs
As for why, these are considered 'one of a kind' items (think about Tsun armor) without a specific different mesh for females (or vice versa) and that doesn't work with all different combination of apparel/clothes.
If you get the ID code you can equip them on your character via console. Chances are, however, they will glitch or they will not be shown in the inventory at all