Don't know about the silver, but I have Molag Bal's mace at Legendary, as well as Dawnbreaker.
Dawnbreaker is ebony, not Daedric.
As for getting your smithing skill up, I go out into the wilds and kill as much game as I can, take their pelts, and bring them into town and make leather out of them. Then I just make piece after piece of Leather armor until I run out of materials. It's inexpensive and light, so it's fairly easy to get rid of and if you have other things you can do until the shop opens, you don't stand as much of a chance of being over encumbered. When I do that, I get a skill increase every 2 or 3 pieces, so it adds up pretty quick but your supplies diminish even quicker. You can get free skill increases and around a couple hundred in coin so I'd say it pays off pretty well.