I think you mean Fallout 2. And I while I can't directly answer your question (I'm opposing the NCR from start to finish), if you have a high fame with them they will basically treat you as one of their own, and you can wear their armor to be seen as such by anyone else (many NPCs will comment on it, and you can... omite the truth).
However, the game so far has hinted that only elite rangers get their best armor (likely the one featured in promotional artwork) and therefore I believe you can't just go up to them and buy it, so I'm guessing you have to join them to obtain it (or kill one of such elites if you oppose them).