1. I want to change the model for a certain item, so that it looks like another item that is in the game. I am guessing I need to export models somehow?
If you wish to change the model of an existing item (why? o_o) then just extract the mesh and the corresponding texture files you want the final item to have, use nifskope to point the texture files for the newly copypasted and renamed mesh files (if this is even necessary) and then just move your new files into their corresponding folders under the Skyrim\Data\ folder.
If you for example want to change the mesh of an iron dagger into that of a steel dagger, you need to
1. extract the steel dagger mesh (and probably textures)
2. rename the extracted files to have the same name as the old iron dagger files (eg. irondagger.nif, 1stpersonirondagger.nif etc..)
3. move the renamed files into the Skyrim\Data\Meshes\Weapons\weaponname\ folder (and same for textures, just Skyrim\Data\Textures\Weapons\weaponname\).
This should change the mesh of Iron Dagger into that of a Steel Dagger.
I almost got confused myself while writing this. Ehhh.
Adding a custom item is a tad more work, though it's not hard. You should be able to find lots of tutorials for that on YouTube alone.