First lets get started with the official description of the perk 'Concentrated Fire':
Chance to hit any body part in V.A.T.S. increases slightly with each subsequent hit on that body part.
The Concentrated Fire perk, maybe one of the biggest mysyteries in Fallout.
Nobody is clear on what is actually does.
My question to the developers of Fallout is:
Does the extra percent chance to hit, add after each shot/que or (as the description reads) after each HIT...?
Now, the description says 'hit' so the're should be no debate right?
Wrong!
Because the V.A.T.S. adds percentage (chance), BEFORE you even shot....
So please, someone: answer my question!

Note that you must be an official developer/coder to answer this.
Normal users like me (yes, even with GECK knowledge) can only guess.
Of course everyone if free to debate.
Thanks in advance for your responses.