Check the wiki but I'm pretty sure Aela will now turn you into a werewolf multiple times.
I'm curious could you get werewolf, and then go to serana and get vl. Or do you have to do the quest line as a werewolf
Hmm, I'm not sure about becoming a werewolf again. I would hope that you could be, but from my small amount of knowledge, I do not think you can.
I was a VL and did not like the effects that it had during the day, so I become a werewolf using the Companions quest while I was a VL. I don't think it will have any effect on what happens in the quest for either side if you are one or the other.