More spells become available from the College as you level. Around 35 or so you should be able to get “Ebonyflesh”, which is what my current Arcane Archer uses.
Spell Tome availability is not based on your character level, but rather on your skill level in the relevant school of magic. Each level of spells becomes available at 10 skill less than the appropriate perk that reduces casting costs for those spells becomes available.
For example, Adept spells have a perk to reduce costs available at 50 skill level, so spell tomes for those spells become available at 40 skill level from vendors that are set up to sell them. What vendor sells what is important to know as only the college spell vendors sell the higher level tomes in the base game, meaning you'll never find Expert or Master level spells available for sale anywhere else but at the college vendors for each spell school. The court wizards will typically sell Destruction Adept level spells once you reach appropriate skill levels with a few exceptions. The Riften court wizard Wylandriah, for example, sells Adept level Alteration spells when you reach 40 skill in Alteration.
The levels for spells sold from relevant vendors are as follows:
Novice - always available
Apprentice - always available (15 really but you start the game with at least 15 in all magic schools so they'll always appear)
Adept - 40 skill level in the matching skill
Expert - 65 skill level in the matching skill
Master - 90 skill level in the matching skill, completing a Master level quest from the college's Master teacher is also required