Okay so here is the deal for those with Realtek HD audio:
The program has certain special features where it has sound effects like echoing and sound environments from Sewers to Concert Halls.
I, and others, have noticed that Skyrim's volume is a bit lower than other games. Buuuut...I am sure we are not ones to really mess with the .ini file and constantly adjust numbers for hours until it is satisfactory and then somehow the .ini resets (Same with the volume settings ingame...Been there with Oblivion.ini

So I have found a simple solution. Some may like it, some don't. Feel free to comment in a respective manner

Without further adieu....
Go to your Realtek HD cotnrol panel. Should look like this in the system tray:
http://i956.photobucket.com/albums/ae50/tgl_2010/Untitled-14.png
Then go to the 'Speakers' tab and click on 'Live'. If you do not like it, just click on 'Reset' Or click 'None' in the drop down menu:
http://i956.photobucket.com/albums/ae50/tgl_2010/Untitled1.png
Simple as that...

Alternative solution:
What I did to fix the problem, based on someones post on some other forum. I enabled 5.1 through my Realtek HD Audio Manager and disabled the speakers I dont have, since I have stereo speakers.
That fixed all the low volume problems I had before.
That fixed all the low volume problems I had before.