Action boy gives you +20 AP, somewhat useful if your Agility is low or to add 1 more chance to your V.A.T.S.
Center of mass is useful if you use V.A.T.S. alot but don't want to rely on trying for a headshot all the time to drop a target faster.
I would go with Center of Mass because there are way better action point perks available like Grim Reapers sprint and Nerves of Steel.