Never understood the desire to chase achievements, personally.
But that particular one is an easy one to get, my current character has about 300k, and the one before that topped a million in vanilla. I don't think there are any particular money-spinners in Dawnguard, get it if you want to do the quests and enjoy the story (and the side-quest Lost to the Ages is IMO one of the best quests ever to appear in a BGS game), but IMO if it's come down to people buying games or DLC where their only interest is in getting an achievement, then that is a sorry state of affairs for the future of gaming.
Best way to make money is either to make potions, or enchant basic armor from loot, and sell the products that you make.