Well personally yes, and as a Shadowscale Argonian Vampire his justification for serving the TG is to honor the Night Mother who is connected to Sithis directly by supposidley being his wife (or was), Reason: she used to be a member of the thieves guild, explanation below, and so by honoring where the Night Mother began her illustrious career i am honoring her and sithis as they are wed (or is beleived thats the case) i also perform assinations while im in the DB though not for there jobs as that i beleive would insult the integeraty of the Night Mother.
I will honor anything connected to Sithis so he can fully see my Devotion, although i will not let it or anyone control who i am or what i do, if i disagree with something i well not hesitate to refuse.
His RP is complicated and has been going since morrowind, il lwrite you the whole thing if you like though im not at home at the moment so i cant copy / Paste it

haha.
Guild affiliation
she was a member of the http://elderscrolls.wikia.com/wiki/Thieves_Guild, around the time when it was just beginning. She was one of many at the time that found it easier to just strangle the occupant of the house, rather than go through the bother of sneaking the entire time. She suggested the Guild have a special group of those who specialized in such a task, just as there were for http://elderscrolls.wikia.com/wiki/Pickpocket, http://elderscrolls.wikia.com/wiki/Lockpicking, http://elderscrolls.wikia.com/wiki/Fence, etc., but they decided encouraging murder would be bad for business and refused. However, realizing the possible profits from killing for hire, the Night Mother began performing assassinations, and left a calling card of two stones, one white and one black, in each eye. The following she developed did not become the http://elderscrolls.wikia.com/wiki/Morag_Tong, however. According to her supposed words, the Morag Tong existed long before her time, and she merely took on those members that split from the group after the murder of the last Potentate, as she was "the only other murder syndicate of any note". According to the editor's note at the end of the book, the book was originally published anonymously, but that anyone can recognize the familiar writing and cadence of http://elderscrolls.wikia.com/wiki/Enric_Milres. It goes on to say that shortly after the publishing of this book, Milres was found "strangled, and two stones, a black one and a white one, crushed into his eye-sockets. Very brutally."