You get your smith skill up by making weapons. It's easy get some leather by killing some animals for skin. Turn into leather and leather strips. Make same leather armor and there you go your skill goes up. You can make any item on the list as long as its highlighted, if it's not then below the item you'll see what you need in order to create that item. Then you go get, find it exploring or buy it. There are very easy ways to get your smith skill up very quickly. Just make a ton of iron daggers or leather braces, you don't need much at all to create these items. Be warned that you may become to powerful by leveling up smithing to quickly. I call doing it that way cheating. I have been known to sit there and make a few extra daggers because I had the materials to make them but still it's called cheating and is not reccomended. Then when you start to level smithing up you can start spending perk points in the skill to make different types of weapons and armor. The left side of the perk tree is for light armor and the right is for heavy armor. Plus each side has weapons for everyone to use so if your in it to be a full blacksmith you might want to go up both sides of the tree.
Enchanting. Find an enchanting table. Easy access one is in Dragonsreach in Whiterun. You disenchant an item you have in your inventory to learn the enchantment, the item is destroyed by doing this. Once the enchantment is learned you can pick an item and an enchantment you have learned and enchant that item. You need soil gems to do this the bigger souls the more powerful the enchantment becomes. Also you eventually start to put perk in your enchantment tree to make the enchantments more powerful. If you go to an enchanter it should explain how to use it for the first time.