Here's the workaround for the hotkeys assignments:
http://www.gamesas.com/index.php?/topic/1136139-ctd-on-hotkey-assign-fix/
If you can't access the pipboy at all, you might want to try the console command:
ResetPipboyManager
I have never used this command but according to the http://geck.gamesas.com/index.php/ResetPipboyManager it allows you to use the pipboy, usually after equiping it but there could be a bug where yours is acting like it isn't equipped.
If not, you can try adding then equiping your pipboy in the console:
player.AddItem 15038 1
player.EquipItem 15038
ResetPipboyManager
and then you can try to add the glove if it doesn't show up:
player.AddItem 25B83 1
player.EquipItem 25B83
Again, I'm not sure any of this will work but I hope it does. I don't usually do a lot w/ item manipulation in the console. I'm piecing this together from the console commands list:
http://fallout.wikia.com/wiki/Gamebryo_console_commands