Ok, basically you have.
Lead, to make the bullet with.
Powder to propel it.
A casing or shell (shells go into shotguns) to hold it all
a primer to set the powder off.
Led is universal
Powder is according to guns, like .22 powder is not going to work for a 10MM.
Primers are going with small or large hand gun and s/l rifles.
Casing are self explained.
for eaxmple
1 10MM casing
1 large pistol primer
X led
X large handgun powder
=
1 10MM round.
This is much more in-depth than what FO3 /w FWE had... but some niggles:
Powder is, for the most part, powder. There's no such thing as "large handgun powder" vs "small handgun powder"
Rimfire doesn't have a separate primer. It's put right into the bottom of the casing and 'spun' into the rim. (.22 is like this). For that matter, primers are primers. They aren't any different because the cartridge is a bit wider.
Also, the game also calls shells/casings 'hulls' for some ammunition.
Good ideas, shaky implementation. Whomever fleshed it out, hasn't spent much time with real firearms.