I just found http://www.creationkit.com/Adding_Voice_Intermediate_Tutorial - lol.

Further, to convert .wav to .xwm - basically to make sound files much smaller, use this mod by vikichan - I have not tested it yet though.
With a little planning, all .wav files for voice acting can be made ahead of use and if .wav is used, the linked mod will easily convert the .wav to the much smaller CK friendly .xwm - really good for keeping file size of mod down.
You could even (as far as iI can see) use temporary .wav while making mod then convert - finished - .wav to .xwm and switch the files over - through CK and remembering to redo lip sync.
