Fat chance, my hood just turned white.
Yeah, it does that every now and then.

I was moaning about not being able to improve anything above flawless except steel and elven weapons. It's odd that my iron daggers won't improve above flawless but steel blades will go to legendary.
I just checked this and I couldn't get Iron Daggers to Legendary without wearing my 4 * +25% Fortify Smithing Gear either. So if it's a bug I'm experiencing the same one. I'd call it more of an oversight by Bethesda since Steel is the first Perk there isn't one for Iron, but we should be able to smith iron to Legendary with Smithing at 100.

The problem with Dark Brotherhood, Nightingale, &c, is they are enchanted. I'm learning the hard way that enchanted items won't temper to Legendary even with Smithing 100 and all perks taken unless I have going for me a lot of fortify Smithing.
I think it's more about them being leather than being enchanted. I can't get 'normal' Leather armor to Legendary without gear and potions. I do think it's odd that there is no perk for Leather - they should lump it into "Advanced Armors" especially since Plate is Heavy, but it's perk is on the Light side.

What's annoying is I've not found a single Fortify Smithing item of apparel that I can use to learn the enchantment from.
Damn. I guess just do the vendor loop until you find someone selling it. Warmaiden's, Riverwood Traders, Radiant Raiment, and Riften Blacksmith have had good enchanted items in my and other's experiences.
