Personally I use the slow-time shout most often. Walking into a tight room filled with fire mages and dual-wielding with light armour? Helps a bunch to dodge those first few bolts and get in there and power attack them down fast.
Unrelenting force I use it high places, knocking things off a cliff never gets old.
Marked for death I definitely use on the elder/ancient dragons (I play on master difficulty and their fire breath one-hits you) anything to kill them fast.
Call Dragon when I'm up against 2 dragons and/or Call or Valour.
Throw Voice/Disarm/Dismay good for getting the hell out of somewhere quick.
Whirlwind Sprint because walking svcks + hidden ledges

Oh and sometime I use Clear Skies as the snow falling constantly in your face can be a bit of a handicap in a fight, especially when bandits are sniping you though the trees.