2 - Lady Killer
4 - Educated
6 - Lead Belly or Bloody Mess
8 - Strong Back
10 - Animal Friend
12 - Long Haul or Robotics Expert
14 - Admantium Skeleton or possibly Jury Rigging
16 - Tag! or maybe Better Criticals.
18 - Computer Whiz, maybe? (the level 18 skills doesn't look too attractive to me, but...)
20 - Grim Reaper's Sprint or Solar Powered?
Those above 20 doesn't look that tempting to me, expect maybe Rad Absorption. I may also change muy mindf as my character develops. This list of mine is, however just a list of the perks that I may be interested in choosing for my character, but they're not the final choice by any means. Also, I'm likely to take Intense Training once or twice as well...
Overall I guess my character will be a sort of survivor/trader/smooth talker kind of character.