Every time I try to rebind the F key I am no long able to set favorites in the item menu!
I hit the F key, I try clicking favorites, but it don't freaking work. Any ideas?
Wait for a patch. (If Bethesda even cares)
keyboard re-binding in general is simply not working properly on the PC, (For many of us lefties the game is pretty much unplayable because of this, i stopped at the end of the introduction and simply won't bother until it is fixed, gonna try to get a refund from steam if its not fixed before next friday).
There has however been people mentioning third party key rebinding software you can use to remap your keys entierly while the game is running (This however also affects things like typing in your name, but since that is only done once per game its probably not a big deal)
Check this thread: http://www.gamesas.com/index.php?/topic/1257110-keybinds-to-numpad/